Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

Hiroko Aiso; Takuya Kochi; Hitoshi Mutsutani; Takamasa Tanabe; Shigeru Nishiyama; Fumitoshi Kakiuchi

doi:10.1021/jo3012286

Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

Hiroko Aiso, Takuya Kochi, Hitoshi Mutsutani, Takamasa Tanabe, Shigeru Nishiyama, Fumitoshi Kakiuchi

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研究成果: Article › 査読

96 被引用数 (Scopus)

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Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

本文言語	English
ページ（範囲）	7718-7724
ページ数	7
ジャーナル	Journal of Organic Chemistry
巻	77
号	17
DOI	https://doi.org/10.1021/jo3012286
出版ステータス	Published - 2012 9月 7

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有機化学

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10.1021/jo3012286

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abstract = "Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.",

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AU - Aiso, Hiroko

AU - Kochi, Takuya

AU - Mutsutani, Hitoshi

AU - Tanabe, Takamasa

AU - Nishiyama, Shigeru

AU - Kakiuchi, Fumitoshi

PY - 2012/9/7

Y1 - 2012/9/7

N2 - Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

AB - Palladium-catalyzed electrochemical iodination and one-pot arylation of arylpyridines are described. Ortho-selective C-H iodination proceeded via dual activation of each substrate by a palladium catalyst and an electrode. Various aryl groups were introduced at the ortho positions of arylpyridines by ON/OFF switching of two different catalytic cycles using the same palladium catalyst in a one-pot fashion.

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Catalytic electrochemical C-H iodination and one-pot arylation by ON/OFF switching of electric current

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