Co-Fe Prussian Blue analogue intercalated into diamagnetic Mg-Al layered double hydroxides

研究成果: Article査読

3 被引用数 (Scopus)

抄録

A heterostructure of diamagnetic magnesium-aluminium layered double hydroxides (Mg-Al LDHs) and photomagnetic cobalt-iron Prussian Blue analogue (Co-Fe PBA) was designed, synthesized and then designated as LDH-PB. The cyanide-bridged Co-Fe PBA was two-dimensionally intercalated into the Mg-Al LDH template by the stepwise anion exchange method. LDH-PB showed ferrimagnetic properties with in-plane antiferromagnetic exchange interactions, as well as small photo-induced magnetization by visible light illumination due to the low dimensional structures and the characteristic photo-induced electronic states of the mixed valence of FeIII(low spin, S = 1/2)-CN-CoII(high spin, S = 3/2)-NC-FeII (low spin, S = 0).

本文言語English
論文番号63276
ジャーナルNanomaterials and Nanotechnology
6
1
DOI
出版ステータスPublished - 2016

ASJC Scopus subject areas

  • バイオテクノロジー
  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • 電子工学および電気工学

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