Concise synthesis of α-trisubstituted amines from ketones using n -methoxyamines

Yusuke Kurosaki; Kenji Shirokane; Takeshi Oishi; Takaaki Sato; Noritaka Chida

doi:10.1021/ol300622r

Concise synthesis of α-trisubstituted amines from ketones using n -methoxyamines

Yusuke Kurosaki
, Kenji Shirokane
, Takeshi Oishi
, Takaaki Sato
, Noritaka Chida

研究成果: Article › 査読

27 被引用数 (Scopus)

抄録

Three-component allylation and cyanation utilizing a ketone and an N-methoxyamine are reported. The high nucleophilicity of the N-methoxyamine and high electrophilicity of the corresponding iminium ion enable the concise synthesis of α-trisubstituted amines in a single step.

本文言語	English
ページ（範囲）	2098-2101
ページ数	4
ジャーナル	Organic Letters
巻	14
号	8
DOI	https://doi.org/10.1021/ol300622r
出版ステータス	Published - 2012 4月 20

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol300622r

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title = "Concise synthesis of α-trisubstituted amines from ketones using n -methoxyamines",

abstract = "Three-component allylation and cyanation utilizing a ketone and an N-methoxyamine are reported. The high nucleophilicity of the N-methoxyamine and high electrophilicity of the corresponding iminium ion enable the concise synthesis of α-trisubstituted amines in a single step.",

author = "Yusuke Kurosaki and Kenji Shirokane and Takeshi Oishi and Takaaki Sato and Noritaka Chida",

year = "2012",

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T1 - Concise synthesis of α-trisubstituted amines from ketones using n -methoxyamines

AU - Kurosaki, Yusuke

AU - Shirokane, Kenji

AU - Oishi, Takeshi

AU - Sato, Takaaki

AU - Chida, Noritaka

PY - 2012/4/20

Y1 - 2012/4/20

N2 - Three-component allylation and cyanation utilizing a ketone and an N-methoxyamine are reported. The high nucleophilicity of the N-methoxyamine and high electrophilicity of the corresponding iminium ion enable the concise synthesis of α-trisubstituted amines in a single step.

AB - Three-component allylation and cyanation utilizing a ketone and an N-methoxyamine are reported. The high nucleophilicity of the N-methoxyamine and high electrophilicity of the corresponding iminium ion enable the concise synthesis of α-trisubstituted amines in a single step.

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UR - https://www.scopus.com/pages/publications/84860161791#tab=citedBy

U2 - 10.1021/ol300622r

DO - 10.1021/ol300622r

M3 - Article

C2 - 22475208

AN - SCOPUS:84860161791

SN - 1523-7060

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SP - 2098

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JO - Organic Letters

JF - Organic Letters

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Concise synthesis of α-trisubstituted amines from ketones using n -methoxyamines

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