Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands

Akira Ikezaki; Hideyuki Tukada; Mikio Nakamura

doi:10.1039/b800674a

Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands

Akira Ikezaki, Hideyuki Tukada, Mikio Nakamura

放射線科学

研究成果: Article › 査読

15 被引用数 (Scopus)

抄録

Addition of tert-butylisocyanide (^tBuNC) to a CD ₂Cl₂ solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(^tBuNC)₂] ²⁺, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)₂]²⁺; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.

本文言語	English
ページ（範囲）	2257-2259
ページ数	3
ジャーナル	Chemical Communications
号	19
DOI	https://doi.org/10.1039/b800674a
出版ステータス	Published - 2008

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学一般
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/b800674a

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abstract = "Addition of tert-butylisocyanide (tBuNC) to a CD 2Cl2 solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2] 2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.",

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doi = "10.1039/b800674a",

language = "English",

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journal = "Chemical Communications",

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T1 - Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands

AU - Ikezaki, Akira

AU - Tukada, Hideyuki

AU - Nakamura, Mikio

PY - 2008

Y1 - 2008

N2 - Addition of tert-butylisocyanide (tBuNC) to a CD 2Cl2 solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2] 2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.

AB - Addition of tert-butylisocyanide (tBuNC) to a CD 2Cl2 solution of the bis(perchlorato)(meso- tetramesitylporphyrinato) iron(iii) cation radical leads to the formation of the corresponding bis(adduct), [Fe(TMP)(tBuNC)2] 2+, whose electronic structure is in sharp contrast to that of the corresponding imidazole(HIm) complex, [Fe(TMP)(HIm)2]2+; the former adopts the S = 0 while the latter exhibits the S = 1 electronic ground state.

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JO - Chemical Communications

JF - Chemical Communications

IS - 19

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Control of electronic structure of a six-coordinate iron(III) porphyrin radical by means of axial ligands

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