@article{330f572271ce45e495bbdcff5f999efb,
title = "Desymmetrization of prochiral methylenes by asymmetric chain-walking cyclization using bioxazoline palladium catalysts",
abstract = "We present here that the use of bioxazoline ligands improved the enantioselectivity of the palladium-catalyzed chain-walking cycloisomerization of 1,n-dienes. The new system was applied to the asymmetric chain-walking cycloisomerization of a variety of 1,n-dienes as well as asymmetric hydrosilylation/cyclization of a 1,8-diene.",
keywords = "Asymmetric cycloisomerization, Bioxazoline ligands, Chain walking, Palladium catalysts, Remote Functionalization",
author = "Masayuki Shigekane and Tomonori Arai and Makoto Tamura and Tatsuya Uchida and Fumitoshi Kakiuchi and Takuya Kochi",
note = "Funding Information: This work was supported, in part, by JSPS KAKENHI Grant Numbers 22H02085 (Grant-in-Aid for Scientific Research (B)), 18H01985 (Grant-in-Aid for Scientific Research (B)), and 18H04271 (Precisely Designed Catalysts with Customized Scaffolding). Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",
year = "2023",
month = jan,
day = "12",
doi = "10.1016/j.tetlet.2022.154292",
language = "English",
volume = "114",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
}