Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

Shunsuke Onodera; Soya Ishikawa; Takuya Kochi; Fumitoshi Kakiuchi

doi:10.1021/jacs.8b03718

Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

Shunsuke Onodera, Soya Ishikawa, Takuya Kochi, Fumitoshi Kakiuchi

化学科

研究成果: Article › 査読

73 被引用数 (Scopus)

抄録

A novel method for direct transformation of allyl groups in allylbenzene derivatives to alkenyl groups via rhodium-catalyzed C-C bond cleavage is reported. The alkenylation with styrenes of allylbenzenes containing pyridyl and pyrazolyl groups as a directing group proceeded efficiently to give alkenylation products. We also developed a new protocol for transformation of an ortho-prenylated phenol to an aniline derivative.

本文言語	English
ページ（範囲）	9788-9792
ページ数	5
ジャーナル	Journal of the American Chemical Society
巻	140
号	31
DOI	https://doi.org/10.1021/jacs.8b03718
出版ステータス	Published - 2018 8月 8

ASJC Scopus subject areas

触媒
化学一般
生化学
コロイド化学および表面化学

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10.1021/jacs.8b03718

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AU - Kakiuchi, Fumitoshi

PY - 2018/8/8

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Direct Alkenylation of Allylbenzenes via Chelation-Assisted C-C Bond Cleavage

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