Direct catalytic asymmetric mannich-type reaction of α-sulfanyl lactones

Sho Takechi; Naoya Kumagai; Masakatsu Shibasaki

doi:10.1021/ol4008734

Direct catalytic asymmetric mannich-type reaction of α-sulfanyl lactones

Sho Takechi
, Naoya Kumagai
, Masakatsu Shibasaki

研究成果: Article › 査読

20 被引用数 (Scopus)

抄録

Catalytic asymmetric Mannich-type reactions of α-sulfanyl lactones to aldimines were promoted by a chiral Ag complex/DBU binary catalyst. The reaction proceeded in a syn-selective manner in high enantioselectivity. Alkylative activation of the sulfide of the Mannich adduct allowed for the formation of trisubstituted aziridines.

本文言語	English
ページ（範囲）	2632-2635
ページ数	4
ジャーナル	Organic Letters
巻	15
号	11
DOI	https://doi.org/10.1021/ol4008734
出版ステータス	Published - 2013 6月 7
外部発表	はい

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol4008734

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title = "Direct catalytic asymmetric mannich-type reaction of α-sulfanyl lactones",

abstract = "Catalytic asymmetric Mannich-type reactions of α-sulfanyl lactones to aldimines were promoted by a chiral Ag complex/DBU binary catalyst. The reaction proceeded in a syn-selective manner in high enantioselectivity. Alkylative activation of the sulfide of the Mannich adduct allowed for the formation of trisubstituted aziridines.",

author = "Sho Takechi and Naoya Kumagai and Masakatsu Shibasaki",

year = "2013",

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AU - Takechi, Sho

AU - Kumagai, Naoya

AU - Shibasaki, Masakatsu

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Y1 - 2013/6/7

N2 - Catalytic asymmetric Mannich-type reactions of α-sulfanyl lactones to aldimines were promoted by a chiral Ag complex/DBU binary catalyst. The reaction proceeded in a syn-selective manner in high enantioselectivity. Alkylative activation of the sulfide of the Mannich adduct allowed for the formation of trisubstituted aziridines.

AB - Catalytic asymmetric Mannich-type reactions of α-sulfanyl lactones to aldimines were promoted by a chiral Ag complex/DBU binary catalyst. The reaction proceeded in a syn-selective manner in high enantioselectivity. Alkylative activation of the sulfide of the Mannich adduct allowed for the formation of trisubstituted aziridines.

UR - https://www.scopus.com/pages/publications/84879237763

UR - https://www.scopus.com/pages/publications/84879237763#tab=citedBy

U2 - 10.1021/ol4008734

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M3 - Article

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AN - SCOPUS:84879237763

SN - 1523-7060

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JO - Organic Letters

JF - Organic Letters

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Direct catalytic asymmetric mannich-type reaction of α-sulfanyl lactones

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