Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

Masaki Okamoto; Takuya Asano; Eiichi Suzuki

doi:10.1023/A:1014992915564

Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

Masaki Okamoto
, Takuya Asano
, Eiichi Suzuki

研究成果: Article › 査読

6 被引用数 (Scopus)

抄録

In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

本文言語	English
ページ（範囲）	33-36
ページ数	4
ジャーナル	Catalysis Letters
巻	78
号	1-4
DOI	https://doi.org/10.1023/A:1014992915564
出版ステータス	Published - 2002 3月
外部発表	はい

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触媒
化学一般

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title = "Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts",

abstract = "In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.",

keywords = "Copper catalyst, Direct synthesis, Metallic germanium, Phenylchlorogermane, Silver catalyst",

author = "Masaki Okamoto and Takuya Asano and Eiichi Suzuki",

year = "2002",

month = mar,

doi = "10.1023/A:1014992915564",

language = "English",

volume = "78",

pages = "33--36",

journal = "Catalysis Letters",

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T1 - Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

AU - Okamoto, Masaki

AU - Asano, Takuya

AU - Suzuki, Eiichi

PY - 2002/3

Y1 - 2002/3

N2 - In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

AB - In the direct synthesis of phenylchlorogermanes, copper(I) chloride was the best catalyst among the metal chlorides tested, the products being diphenyldichlorogermane and phenyltrichlorogermane. The reaction mainly gave diphenyldichlorogermane; however at the beginning of the reaction, phenyltrichlorogermane was afforded by the reaction of chlorobenzene and dichlorogermylene formed from metallic germanium and chloride ion in the catalyst.

KW - Copper catalyst

KW - Direct synthesis

KW - Metallic germanium

KW - Phenylchlorogermane

KW - Silver catalyst

UR - https://www.scopus.com/pages/publications/0036493926

UR - https://www.scopus.com/pages/publications/0036493926#tab=citedBy

U2 - 10.1023/A:1014992915564

DO - 10.1023/A:1014992915564

M3 - Article

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SN - 1011-372X

VL - 78

SP - 33

EP - 36

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-4

ER -

Direct synthesis of phenylchlorogermanes from metallic germanium and chlorobenzene using metal chloride catalysts

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