Directing effect of functional groups in ruthenium-catalyzed addition of substituted acetophonones to an olefin

Motohiro Sonoda; Fumitoshi Kakiuchi; Naoto Chatani; Shinji Murai

doi:10.1016/0022-328X(95)05607-Q

Directing effect of functional groups in ruthenium-catalyzed addition of substituted acetophonones to an olefin

Motohiro Sonoda
, Fumitoshi Kakiuchi
, Naoto Chatani
, Shinji Murai

研究成果: Article › 査読

61 被引用数 (Scopus)

抄録

Ruthenium-catalyzed addition of 3′-methyl-, 3′-trifluoromethyl-, and 3′-N,N-dimethylaminoacetophenones to an olefin proceeds site selectively at 6′ CH bonds to give the 1:1 CH/olefin addition products in high yields. In contrast, the addition of 3′-methoxyacetophenone takes place preferentially at the CH bond at the more congested 2′ position.

本文言語	English
ページ（範囲）	151-152
ページ数	2
ジャーナル	Journal of Organometallic Chemistry
巻	504
号	1-2
DOI	https://doi.org/10.1016/0022-328X(95)05607-Q
出版ステータス	Published - 1995 11月 29
外部発表	はい

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学
無機化学
材料化学

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10.1016/0022-328X(95)05607-Q

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title = "Directing effect of functional groups in ruthenium-catalyzed addition of substituted acetophonones to an olefin",

abstract = "Ruthenium-catalyzed addition of 3′-methyl-, 3′-trifluoromethyl-, and 3′-N,N-dimethylaminoacetophenones to an olefin proceeds site selectively at 6′ CH bonds to give the 1:1 CH/olefin addition products in high yields. In contrast, the addition of 3′-methoxyacetophenone takes place preferentially at the CH bond at the more congested 2′ position.",

keywords = "Acetophenone, Carbon-hydrogen bond cleavage, Catalysis, Catalytic CH/olefin coupling, Ketone, Ruthenium",

author = "Motohiro Sonoda and Fumitoshi Kakiuchi and Naoto Chatani and Shinji Murai",

year = "1995",

month = nov,

day = "29",

doi = "10.1016/0022-328X(95)05607-Q",

language = "English",

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journal = "Journal of Organometallic Chemistry",

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T1 - Directing effect of functional groups in ruthenium-catalyzed addition of substituted acetophonones to an olefin

AU - Sonoda, Motohiro

AU - Kakiuchi, Fumitoshi

AU - Chatani, Naoto

AU - Murai, Shinji

PY - 1995/11/29

Y1 - 1995/11/29

N2 - Ruthenium-catalyzed addition of 3′-methyl-, 3′-trifluoromethyl-, and 3′-N,N-dimethylaminoacetophenones to an olefin proceeds site selectively at 6′ CH bonds to give the 1:1 CH/olefin addition products in high yields. In contrast, the addition of 3′-methoxyacetophenone takes place preferentially at the CH bond at the more congested 2′ position.

AB - Ruthenium-catalyzed addition of 3′-methyl-, 3′-trifluoromethyl-, and 3′-N,N-dimethylaminoacetophenones to an olefin proceeds site selectively at 6′ CH bonds to give the 1:1 CH/olefin addition products in high yields. In contrast, the addition of 3′-methoxyacetophenone takes place preferentially at the CH bond at the more congested 2′ position.

KW - Acetophenone

KW - Carbon-hydrogen bond cleavage

KW - Catalysis

KW - Catalytic CH/olefin coupling

KW - Ketone

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/0001252947

UR - https://www.scopus.com/pages/publications/0001252947#tab=citedBy

U2 - 10.1016/0022-328X(95)05607-Q

DO - 10.1016/0022-328X(95)05607-Q

M3 - Article

AN - SCOPUS:0001252947

SN - 0022-328X

VL - 504

SP - 151

EP - 152

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Directing effect of functional groups in ruthenium-catalyzed addition of substituted acetophonones to an olefin

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ASJC Scopus subject areas

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