Efficient and stereoselective synthesis of the disaccharide fragment of incednine

Takashi Ohtani; Shohei Sakai; Akira Takada; Daisuke Takahashi; Kazunobu Toshima

doi:10.1021/ol202639v

Efficient and stereoselective synthesis of the disaccharide fragment of incednine

Takashi Ohtani, Shohei Sakai, Akira Takada, Daisuke Takahashi, Kazunobu Toshima

応用化学科

研究成果: Article › 査読

8 被引用数 (Scopus)

抄録

Efficient and stereoselective synthesis of a disaccharide fragment, 2-deoxy-4-O-(N′-monodemethyl-d-forosaminyl)-2-methylamino-β-d- xylopyranoside, of a novel antibiotic, incednine (1), is described. The key β-stereoselective formation of a 2,3,4,6-tetradeoxy-4-methylamino glycoside bond was achieved by remote participation-assisted glycosylation.

本文言語	English
ページ（範囲）	6126-6129
ページ数	4
ジャーナル	Organic Letters
巻	13
号	22
DOI	https://doi.org/10.1021/ol202639v
出版ステータス	Published - 2011 11月 18

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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10.1021/ol202639v

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abstract = "Efficient and stereoselective synthesis of a disaccharide fragment, 2-deoxy-4-O-(N′-monodemethyl-d-forosaminyl)-2-methylamino-β-d- xylopyranoside, of a novel antibiotic, incednine (1), is described. The key β-stereoselective formation of a 2,3,4,6-tetradeoxy-4-methylamino glycoside bond was achieved by remote participation-assisted glycosylation.",

author = "Takashi Ohtani and Shohei Sakai and Akira Takada and Daisuke Takahashi and Kazunobu Toshima",

year = "2011",

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doi = "10.1021/ol202639v",

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T1 - Efficient and stereoselective synthesis of the disaccharide fragment of incednine

AU - Ohtani, Takashi

AU - Sakai, Shohei

AU - Takada, Akira

AU - Takahashi, Daisuke

AU - Toshima, Kazunobu

PY - 2011/11/18

Y1 - 2011/11/18

N2 - Efficient and stereoselective synthesis of a disaccharide fragment, 2-deoxy-4-O-(N′-monodemethyl-d-forosaminyl)-2-methylamino-β-d- xylopyranoside, of a novel antibiotic, incednine (1), is described. The key β-stereoselective formation of a 2,3,4,6-tetradeoxy-4-methylamino glycoside bond was achieved by remote participation-assisted glycosylation.

AB - Efficient and stereoselective synthesis of a disaccharide fragment, 2-deoxy-4-O-(N′-monodemethyl-d-forosaminyl)-2-methylamino-β-d- xylopyranoside, of a novel antibiotic, incednine (1), is described. The key β-stereoselective formation of a 2,3,4,6-tetradeoxy-4-methylamino glycoside bond was achieved by remote participation-assisted glycosylation.

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JO - Organic Letters

JF - Organic Letters

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Efficient and stereoselective synthesis of the disaccharide fragment of incednine

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