Electrical conductive and magnetic properties of conjugated tetrathiolate nickel polymers

Naoki Yoshioka; Hiroyuki Nishide; Katsunari Inagaki; Katsunari Inagaki; Eishun Tsuchida

doi:10.1007/BF01033109

Electrical conductive and magnetic properties of conjugated tetrathiolate nickel polymers

Naoki Yoshioka, Hiroyuki Nishide, Katsunari Inagaki, Katsunari Inagaki, Eishun Tsuchida

研究成果: Article › 査読

25 被引用数 (Scopus)

抄録

Three tetrathiolate (tetrathiafulvalenetetrathiolate, ethylenetetrathiolate, and butadienetetrathiolate) nickel polymers are prepared. The polymers contain mixed valence Ni ions and are ESR active based on low-spin d⁸ Ni (III) species. Magnetic susceptibility measurement in the range of 30-60 K suggests and antiferromagnetic interaction between the Ni ions in the polymers. Below 30K a weak ferromagnetic interaction is observed. Chemically oxidized polymers are ESR inactive, while electrical conductivity is greatly enhanced.

本文言語	English
ページ（範囲）	631-636
ページ数	6
ジャーナル	Polymer Bulletin
巻	23
号	6
DOI	https://doi.org/10.1007/BF01033109
出版ステータス	Published - 1990 6月 1
外部発表	はい

ASJC Scopus subject areas

化学 (全般)
凝縮系物理学
ポリマーおよびプラスチック
材料化学

文献へのアクセス

10.1007/BF01033109

他のファイルとリンク

引用スタイル

@article{cf1296e31dbe4f4a9c98c33ca3898e81,

title = "Electrical conductive and magnetic properties of conjugated tetrathiolate nickel polymers",

abstract = "Three tetrathiolate (tetrathiafulvalenetetrathiolate, ethylenetetrathiolate, and butadienetetrathiolate) nickel polymers are prepared. The polymers contain mixed valence Ni ions and are ESR active based on low-spin d8 Ni (III) species. Magnetic susceptibility measurement in the range of 30-60 K suggests and antiferromagnetic interaction between the Ni ions in the polymers. Below 30K a weak ferromagnetic interaction is observed. Chemically oxidized polymers are ESR inactive, while electrical conductivity is greatly enhanced.",

author = "Naoki Yoshioka and Hiroyuki Nishide and Katsunari Inagaki and Katsunari Inagaki and Eishun Tsuchida",

year = "1990",

month = jun,

day = "1",

doi = "10.1007/BF01033109",

language = "English",

volume = "23",

pages = "631--636",

journal = "Polymer Bulletin",

issn = "0170-0839",

publisher = "Springer Verlag",

number = "6",

}

TY - JOUR

T1 - Electrical conductive and magnetic properties of conjugated tetrathiolate nickel polymers

AU - Yoshioka, Naoki

AU - Nishide, Hiroyuki

AU - Inagaki, Katsunari

AU - Tsuchida, Eishun

PY - 1990/6/1

Y1 - 1990/6/1

N2 - Three tetrathiolate (tetrathiafulvalenetetrathiolate, ethylenetetrathiolate, and butadienetetrathiolate) nickel polymers are prepared. The polymers contain mixed valence Ni ions and are ESR active based on low-spin d8 Ni (III) species. Magnetic susceptibility measurement in the range of 30-60 K suggests and antiferromagnetic interaction between the Ni ions in the polymers. Below 30K a weak ferromagnetic interaction is observed. Chemically oxidized polymers are ESR inactive, while electrical conductivity is greatly enhanced.

AB - Three tetrathiolate (tetrathiafulvalenetetrathiolate, ethylenetetrathiolate, and butadienetetrathiolate) nickel polymers are prepared. The polymers contain mixed valence Ni ions and are ESR active based on low-spin d8 Ni (III) species. Magnetic susceptibility measurement in the range of 30-60 K suggests and antiferromagnetic interaction between the Ni ions in the polymers. Below 30K a weak ferromagnetic interaction is observed. Chemically oxidized polymers are ESR inactive, while electrical conductivity is greatly enhanced.

UR - http://www.scopus.com/inward/record.url?scp=0025448512&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0025448512&partnerID=8YFLogxK

U2 - 10.1007/BF01033109

DO - 10.1007/BF01033109

M3 - Article

AN - SCOPUS:0025448512

SN - 0170-0839

VL - 23

SP - 631

EP - 636

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 6

ER -

Electrical conductive and magnetic properties of conjugated tetrathiolate nickel polymers

抄録

ASJC Scopus subject areas

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル