Electrochemical synthesis and redox properties of a polyruthenocene electrode film

Tadashi Shimura, Kunitsugu Aramaki, Hiroshi Nishihara

研究成果: Article査読

7 被引用数 (Scopus)

抄録

A thin and uniform polyruthenocene film was prepared by electroreduction of [Ru(η5-C5H5)(η5-C 5H4Cl=CHCHO)] in acetonitrile and its electrochemical properties were investigated by cyclic voltammetry. This film undergoes a moderately reversible oxidation, the mechanism of which is explainable as an ECE reaction with a slow chemical step. The kinetics of the chemical step are first-order to the ruthenocene concentration and depend on both solvent and electrolyte anion. The kinetic constant is higher at larger donor number of solvent, lower viscosity of solvent and/or higher coordinating ability of electrolyte anion, implying the competitive coordination of both solvent and electrolyte anion.

本文言語English
ページ(範囲)219-223
ページ数5
ジャーナルJournal of Electroanalytical Chemistry
403
1-2
DOI
出版ステータスPublished - 1996 2月 21

ASJC Scopus subject areas

  • 分析化学
  • 化学工学一般
  • 電気化学

フィンガープリント

「Electrochemical synthesis and redox properties of a polyruthenocene electrode film」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル