@inproceedings{37894d17425b412b93b69a654a0bdc00,
title = "Electrodeposition of platinum in some amide-type ionic liquids containing Bis(acetylacetonato)platinum(II)",
abstract = "Electrodeposition of platinum (Pt) from bis(acetylacetonato)platinum(II) (Pt(acac)2) has been investigated in bis(trifluoromethylsulfonyl)amide (TFSA-) ionic liquids composed of 1-butyl-1-methylpyrrolidinium (BMP+), 1-hexyl-1-methylpyrrolidinium (HMP+) and 1-decyl-1-methylpyrrolidinium (DMP+). Pt(acac)2 was found to be electrochemically reduced to Pt(0) in each ionic liquid. Reduction of Pt(acac)2 was suggested to involve formation and disproportionation of some intermediate species of Pt by cyclic voltammetry. Potentiostatic cathodic reduction at -1.7 V resulted in deposition of Pt and Pt nanoparticles dispersed in the ionic liquid. The average sizes (in diameter) of the Pt nanoparticles were found to be 2.6 ± 0.7, 4.1 ± 1.2 and 4.3 ± 0.7 nm in BMPTFSA, HMPTFSA and DMPTFSA, respectively. The average particle sizes of the Pt nanoparticles tended to increase with an increase in the alkyl chain length of the cations of the ionic liquids.",
author = "Sharmin Sultana and Naoki Tachikawa and Kazuki Yoshii and Luca Magagnin and Yasushi Katayama",
year = "2016",
doi = "10.1149/07515.0617ecst",
language = "English",
series = "ECS Transactions",
publisher = "Electrochemical Society Inc.",
number = "15",
pages = "617--625",
editor = "Haverhals, \{L. M.\} and Mantz, \{R. A.\} and Trulove, \{P. C.\} and M. Ueda and M. Carter and Biddinger, \{E. J.\} and Suroviec, \{A. H.\} and M. Reichert and F. Endres and A. Bund and A. Ispas and Fox, \{D. M.\} and \{De Long\}, \{H. C.\}",
booktitle = "Molten Salts and Ionic Liquids 20",
edition = "15",
note = "Symposium on Molten Salts and Ionic Liquids 20 - PRiME 2016/230th ECS Meeting ; Conference date: 02-10-2016 Through 07-10-2016",
}