Enantioselective borohydride reduction of N-diphenylphosphinyl imines using optically active cobalt(II) complex catalysts

Kiyoaki D. Sugi, Takushi Nagata, Tohru Yamada, Teruaki Mukaiyama

研究成果: Article査読

83 被引用数 (Scopus)

抄録

The enantioselective borohydride reduction using optically active cobalt(II) complex catalysts was successfully applied to various aryl N-diphenylphosphinyl imines, and the corresponding reduced products were obtained in good yields with high enantiomeric excesses (up to 99% ee). The optically active primary amines were obtained by the successive hydrolysis under mild conditions.

本文言語English
ページ(範囲)493-494
ページ数2
ジャーナルChemistry Letters
6
DOI
出版ステータスPublished - 1997
外部発表はい

ASJC Scopus subject areas

  • 化学一般

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