TY - JOUR
T1 - Enantioselective ene reaction of cyclopentadiene and α,β-enals catalyzed by a diphenylprolinol silyl ether
AU - Gotoh, Hiroaki
AU - Masui, Ryouhei
AU - Ogino, Hiroshi
AU - Shoji, Mitsuru
AU - Hayashi, Yujiro
PY - 2006/10/20
Y1 - 2006/10/20
N2 - (Chemical Equation Presented) The opposite result: A diphenylprolinol silyl ether promotes an intermolecular enantioselective ene reaction of α,β-enals with cyclopentadiene. This is the first example of cyclopentadiene acting as the ene component, and not the diene, with α,β-enals.
AB - (Chemical Equation Presented) The opposite result: A diphenylprolinol silyl ether promotes an intermolecular enantioselective ene reaction of α,β-enals with cyclopentadiene. This is the first example of cyclopentadiene acting as the ene component, and not the diene, with α,β-enals.
KW - Asymmetric synthesis
KW - Cyclopentadiene
KW - Diels-Alder reaction
KW - Ene reaction
KW - Organocatalysis
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U2 - 10.1002/anie.200602925
DO - 10.1002/anie.200602925
M3 - Article
C2 - 17001710
AN - SCOPUS:33750440775
SN - 1433-7851
VL - 45
SP - 6853
EP - 6856
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 41
ER -