Enhancement in aerobic alcohol oxidation catalysis of Au25 clusters by single Pd atom doping

Songhai Xie; Hironori Tsunoyama; Wataru Kurashige; Yuichi Negishi; Tatsuya Tsukuda

doi:10.1021/cs300252g

Enhancement in aerobic alcohol oxidation catalysis of Au₂₅ clusters by single Pd atom doping

Songhai Xie
, Hironori Tsunoyama
, Wataru Kurashige
, Yuichi Negishi
, Tatsuya Tsukuda

研究成果: Article › 査読

395 被引用数 (Scopus)

抄録

Au₂₅ and Pd₁Au₂₄ clusters on multiwalled carbon nanotubes were developed via adsorption of Au₂₅(SC ₁₂H₂₅)₁₈ and Pd₁Au ₂₄(SC₁₂H₂₅)₁₈, respectively, on the nanotubes, followed by calcination. Comparison of their catalysis for the aerobic oxidation of benzyl alcohol showed that single Pd atom doping significantly improved the catalytic performance of Au₂₅ for the first time.

本文言語	English
ページ（範囲）	1519-1523
ページ数	5
ジャーナル	ACS Catalysis
巻	2
号	7
DOI	https://doi.org/10.1021/cs300252g
出版ステータス	Published - 2012 7月 6
外部発表	はい

ASJC Scopus subject areas

触媒
化学一般

文献へのアクセス

10.1021/cs300252g

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引用スタイル

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abstract = "Au25 and Pd1Au24 clusters on multiwalled carbon nanotubes were developed via adsorption of Au25(SC 12H25)18 and Pd1Au 24(SC12H25)18, respectively, on the nanotubes, followed by calcination. Comparison of their catalysis for the aerobic oxidation of benzyl alcohol showed that single Pd atom doping significantly improved the catalytic performance of Au25 for the first time.",

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AU - Tsukuda, Tatsuya

PY - 2012/7/6

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AB - Au25 and Pd1Au24 clusters on multiwalled carbon nanotubes were developed via adsorption of Au25(SC 12H25)18 and Pd1Au 24(SC12H25)18, respectively, on the nanotubes, followed by calcination. Comparison of their catalysis for the aerobic oxidation of benzyl alcohol showed that single Pd atom doping significantly improved the catalytic performance of Au25 for the first time.

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KW - multiwalled carbon nanotubes

KW - single Pd atom doping

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