Enzymatic synthesis of biodegradable fumarate oligomer

Nobuyuki Hironaka; Kazunobu Toshima; Shuichi Matsumura

Enzymatic synthesis of biodegradable fumarate oligomer

Nobuyuki Hironaka, Kazunobu Toshima, Shuichi Matsumura

応用化学科

研究成果: Paper › 査読

抄録

Biodegradable fumarate oligomers from dimer to tetramer were selectively prepared by the oligomerization of diethyl fumarate using laccase and hydrogen peroxide in various organic solvents. As a typical example, diethyl fumarate was oligomerized using laccase and hydrogen peroxide in ethanol at 60°C for 24 hours to produce the fumarate trimer in 80% yield. Sodium salt of fumarate trimer was biodegraded by the activated sludge.

本文言語	English
ページ数	1
出版ステータス	Published - 2005 12月 1
イベント	54th SPSJ Symposium on Macromolecules - Yamagata, Japan 継続期間: 2005 9月 20 → 2005 9月 22

Other

Other	54th SPSJ Symposium on Macromolecules
国/地域	Japan
City	Yamagata
Period	05/9/20 → 05/9/22

ASJC Scopus subject areas

工学（全般）

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引用スタイル

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abstract = "Biodegradable fumarate oligomers from dimer to tetramer were selectively prepared by the oligomerization of diethyl fumarate using laccase and hydrogen peroxide in various organic solvents. As a typical example, diethyl fumarate was oligomerized using laccase and hydrogen peroxide in ethanol at 60°C for 24 hours to produce the fumarate trimer in 80% yield. Sodium salt of fumarate trimer was biodegraded by the activated sludge.",

keywords = "Biodegradation, Enzyme, Fumaric acid, Laccase, Oligomer, Oligomerization",

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AU - Hironaka, Nobuyuki

AU - Toshima, Kazunobu

AU - Matsumura, Shuichi

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Biodegradable fumarate oligomers from dimer to tetramer were selectively prepared by the oligomerization of diethyl fumarate using laccase and hydrogen peroxide in various organic solvents. As a typical example, diethyl fumarate was oligomerized using laccase and hydrogen peroxide in ethanol at 60°C for 24 hours to produce the fumarate trimer in 80% yield. Sodium salt of fumarate trimer was biodegraded by the activated sludge.

AB - Biodegradable fumarate oligomers from dimer to tetramer were selectively prepared by the oligomerization of diethyl fumarate using laccase and hydrogen peroxide in various organic solvents. As a typical example, diethyl fumarate was oligomerized using laccase and hydrogen peroxide in ethanol at 60°C for 24 hours to produce the fumarate trimer in 80% yield. Sodium salt of fumarate trimer was biodegraded by the activated sludge.

KW - Biodegradation

KW - Enzyme

KW - Fumaric acid

KW - Laccase

KW - Oligomer

KW - Oligomerization

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M3 - Paper

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T2 - 54th SPSJ Symposium on Macromolecules

Y2 - 20 September 2005 through 22 September 2005

ER -

Enzymatic synthesis of biodegradable fumarate oligomer

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