Equilibrium between Fe(iv) porphyrin and Fe(iii) porphyrin radical cation: New insight into the electronic structure of high-valent iron porphyrin complexes

Akira Ikezaki; Masashi Takahashi; Mikio Nakamura

doi:10.1039/c3cc40319j

Equilibrium between Fe(iv) porphyrin and Fe(iii) porphyrin radical cation: New insight into the electronic structure of high-valent iron porphyrin complexes

Akira Ikezaki, Masashi Takahashi, Mikio Nakamura

放射線科学

研究成果: Article › 査読

13 被引用数 (Scopus)

抄録

UV-Vis, NMR, and Mössbauer studies have revealed that [Fe(TMP)(N ₃)₂], showing the Mössbauer parameters quite similar to those of the ferryl species of MauG, CytP450_BM3, Cyt P450 _CAM, and CPO, exists as equilibrium mixtures of Fe(iv) porphyrin and Fe(iii) porphyrin radical cation.

本文言語	English
ページ（範囲）	3098-3100
ページ数	3
ジャーナル	Chemical Communications
巻	49
号	30
DOI	https://doi.org/10.1039/c3cc40319j
出版ステータス	Published - 2013 4月 18

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学一般
表面、皮膜および薄膜
金属および合金
材料化学

文献へのアクセス

10.1039/c3cc40319j

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引用スタイル

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abstract = "UV-Vis, NMR, and M{\"o}ssbauer studies have revealed that [Fe(TMP)(N 3)2], showing the M{\"o}ssbauer parameters quite similar to those of the ferryl species of MauG, CytP450BM3, Cyt P450 CAM, and CPO, exists as equilibrium mixtures of Fe(iv) porphyrin and Fe(iii) porphyrin radical cation.",

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AU - Nakamura, Mikio

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AB - UV-Vis, NMR, and Mössbauer studies have revealed that [Fe(TMP)(N 3)2], showing the Mössbauer parameters quite similar to those of the ferryl species of MauG, CytP450BM3, Cyt P450 CAM, and CPO, exists as equilibrium mixtures of Fe(iv) porphyrin and Fe(iii) porphyrin radical cation.

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