Formation of α-Monosubstituted propargylamines from terminal alkynes and secondary amines using a (PNO)Rh/Cu Tandem catalyst system

Shotaro Takano; Takuya Kochi; Fumitoshi Kakiuchi

doi:10.1246/cl.170754

Formation of α-Monosubstituted propargylamines from terminal alkynes and secondary amines using a (PNO)Rh/Cu Tandem catalyst system

Shotaro Takano
, Takuya Kochi
, Fumitoshi Kakiuchi

化学科

研究成果: Review article › 査読

14 被引用数 (Scopus)

抄録

A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.

本文言語	English
ページ（範囲）	1620-1623
ページ数	4
ジャーナル	Chemistry Letters
巻	46
号	11
DOI	https://doi.org/10.1246/cl.170754
出版ステータス	Published - 2017

ASJC Scopus subject areas

化学一般

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10.1246/cl.170754

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引用スタイル

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abstract = "A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.",

keywords = "Propargylamines, Rhodium catalysts, Terminal alkynes",

author = "Shotaro Takano and Takuya Kochi and Fumitoshi Kakiuchi",

note = "Publisher Copyright: {\textcopyright} 2017 The Chemical Society of Japan.",

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language = "English",

volume = "46",

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T1 - Formation of α-Monosubstituted propargylamines from terminal alkynes and secondary amines using a (PNO)Rh/Cu Tandem catalyst system

AU - Takano, Shotaro

AU - Kochi, Takuya

AU - Kakiuchi, Fumitoshi

PY - 2017

Y1 - 2017

N2 - A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.

AB - A novel (PNO)Rh/CuBr (PNO: phosphine-quinolinolate) tandem catalyst system was developed for facile synthesis of α-monosubstituted propargylamines from aliphatic terminal al-kynes and secondary amines. Various terminal alkynes and amines were applicable to this reaction and the corresponding propargylamines were obtained in good yields.

KW - Propargylamines

KW - Rhodium catalysts

KW - Terminal alkynes

UR - https://www.scopus.com/pages/publications/85032514650

UR - https://www.scopus.com/pages/publications/85032514650#tab=citedBy

U2 - 10.1246/cl.170754

DO - 10.1246/cl.170754

M3 - Review article

AN - SCOPUS:85032514650

SN - 0366-7022

VL - 46

SP - 1620

EP - 1623

JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -