Formation of cobalt-C60 clusters: Tricapped Co(C60)3 unit

Tsuyoshi Kurikawa, Satoshi Nagao, Ken Miyajima, Atsushi Nakajima, Koji Kaya

研究成果: Article査読

42 被引用数 (Scopus)

抄録

Cobalt (Co)-C60 mixed clusters were produced by the combination of laser vaporization and molecular beam methods. Cationic Con(C60)m+ clusters were produced predominantly with the compositions (n, m) = (0-1, 1), (1, 2), (1, 3), (2-4, 4), and (5, 5). Both mass spectrometry and a chemical probe method have revealed that compositions of (1, 3) and (4, 4) correspond to a tricapped planar structure and a tricapped trigonal pyramid structure, respectively, in which each Co atom is surrounded by three C60.

本文言語English
ページ(範囲)1743-1747
ページ数5
ジャーナルJournal of Physical Chemistry A
102
10
出版ステータスPublished - 1998 3月 5

ASJC Scopus subject areas

  • 物理化学および理論化学

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