Highly active 3-oxobutylideneaminatocobalt complex catalysts for an enantioselective hetero Diels-Alder reaction

S. Kezuka, T. Mita, N. Ohtsuki, T. Ikeno, T. Yamada

研究成果: Article査読

47 被引用数 (Scopus)

抄録

Optically active 3-oxobutylideneaminatocobalt(III) complexes were developed as effective catalysts for the enantioselective hetero Diels-Alder reaction of aromatic and aliphatic aldehydes with 3-(t-butyldimethylsilyloxy)-1-methoxy-1,3-butadiene. In the presence of the highly active cationic cobalt(III) complex, the hetero Diels-Alder reactions proceeded to afford the corresponding dihydropyran-4-ones with high performance and high enantioselectivities. The reaction with aromatic aldehydes substituted by a coordinating group at the ortho position proceeded more smoothly.

本文言語English
ページ(範囲)1333-1342
ページ数10
ジャーナルBulletin of the Chemical Society of Japan
74
7
DOI
出版ステータスPublished - 2001 7月

ASJC Scopus subject areas

  • 化学一般

フィンガープリント

「Highly active 3-oxobutylideneaminatocobalt complex catalysts for an enantioselective hetero Diels-Alder reaction」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル