Highly efficient hydroxylation of gaseous alkanes at reduced temperature catalyzed by cytochrome P450BM3 assisted by decoy molecules

Norifumi Kawakami; Zhiqi Cong; Osami Shoji; Yoshihito Watanabe

doi:10.1142/S1088424615500145

Highly efficient hydroxylation of gaseous alkanes at reduced temperature catalyzed by cytochrome P450BM3 assisted by decoy molecules

Norifumi Kawakami
, Zhiqi Cong
, Osami Shoji
, Yoshihito Watanabe

生命情報学科

研究成果: Article › 査読

8 被引用数 (Scopus)

抄録

Cytochrome P450BM3 functions as a small-alkane hydroxylase upon the addition of perfluorocarboxylic acids (PFs) as decoy molecules. The coupling efficiency (product formation rate per NADPH consumption rate) for the hydroxylation of small alkanes was improved by reducing the reaction temperature to 0°C.

本文言語	English
ページ（範囲）	329-334
ページ数	6
ジャーナル	Journal of Porphyrins and Phthalocyanines
巻	19
号	1-3
DOI	https://doi.org/10.1142/S1088424615500145
出版ステータス	Published - 2015 1月 1

ASJC Scopus subject areas

化学一般

文献へのアクセス

10.1142/S1088424615500145

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引用スタイル

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abstract = "Cytochrome P450BM3 functions as a small-alkane hydroxylase upon the addition of perfluorocarboxylic acids (PFs) as decoy molecules. The coupling efficiency (product formation rate per NADPH consumption rate) for the hydroxylation of small alkanes was improved by reducing the reaction temperature to 0°C.",

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AU - Watanabe, Yoshihito

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KW - decoy molecules

KW - gaseous alkanes

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