Highly enantioselective cyclopropanation of styrenes with diazoacetates catalyzed by optically active β-ketoiminato cobalt(II) complexes

Taketo Ikeno, Mitsuo Sato, Tohru Yamada

研究成果: Article査読

47 被引用数 (Scopus)

抄録

The highly enantioselective cyclopropanation of styrenes with diazoacetates was achieved using reasonably designed β-ketoiminato cobalt(II) complex catalysts. In the presence of optically active cobalt(II) complexes derived from optically active 1,2-(2,4,6-trimethylphenyl)-1,2-ethylenediamine, the cyclopropanation of styrene with methyl, ethyl, and tert-butyl diazoacetates proceeded to afford the corresponding cyclopropanecarboxylates with 94-96% ee.

本文言語English
ページ(範囲)1345-1346
ページ数2
ジャーナルChemistry Letters
12
DOI
出版ステータスPublished - 1999

ASJC Scopus subject areas

  • 化学一般

フィンガープリント

「Highly enantioselective cyclopropanation of styrenes with diazoacetates catalyzed by optically active β-ketoiminato cobalt(II) complexes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル