@article{622b746b92a54a24b7c99adafb00f538,
title = "Highly stereoselective glycosylation by conformational assistance of glycosyl donor",
abstract = "Highly α-stereoselective glycosylation of 2-deoxy-D-fucose was achieved by use of the conformational assistance of the rigid glycosyl donor 2. The selectivity of the glycosylation of 2 was much higher than that of 3 which had a normal chair conformation.",
keywords = "1,3-diaxial interaction., 2-deoxy-D-fucose, anomeric effect, conformational assistance, stereoselective glycosylation",
author = "Kazunobu Toshima and Yuko Nozaki and Kuniaki Tatsuta",
note = "Funding Information: In conclusion, These results suggestedt hatc onformationala ssistanceo f glycosyl donor was an important factor in glycosylation selectivity and could be usedf or controlling the selectivity.F urther,this work showed an effficient method with high stereocontrol for synthesis of 2-deoxy-a-D-fucosides wh::ch were found as componentsi n the antibioticss uch as olivomycinll), Acknowledgement We are gratefult o the Instituteo f Microbial Chemistry for the generouss upporto f our program,F inancial supports by the Ministry of Education, Science and Culture (Grant-in-Aid Scientific Research) and the Kawakami Memorial Foundationa re gratefullya cknowledged.",
year = "1991",
month = nov,
day = "18",
doi = "10.1016/0040-4039(91)80435-9",
language = "English",
volume = "32",
pages = "6887--6890",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "47",
}