TY - JOUR
T1 - Interaction between the peroxide ion and acetato moiety of the ligand system in a cobalt complex with a binucleating ligand
AU - Sasaki, Yumiko
AU - Kobayashi, Teruyuki
AU - Masuda, Hideki
AU - Einaga, Hisahiko
AU - Ohba, Shigeru
AU - Nishida, Yuzo
PY - 1999/6/1
Y1 - 1999/6/1
N2 - Reaction between Na3H2(HXTA) and Na3Co(CO3)3 in an aqueous solution gave a binuclear cobalt(III) complex, Na2Co2(HXTRA), where in the (HXTRA)4- ligand one of the four acetate arms of the (HXTA)5- ligand is lost; H5(HXTA) denotes N,N′-(2-hydroxy-5-methyl-1,3-xylylene)bis(N-carboxymethylglycine). This may be attributed to the oxidative degradation of one acetato arm of the (HXTA)5- ligand due to a peroxide-Co(III) species.
AB - Reaction between Na3H2(HXTA) and Na3Co(CO3)3 in an aqueous solution gave a binuclear cobalt(III) complex, Na2Co2(HXTRA), where in the (HXTRA)4- ligand one of the four acetate arms of the (HXTA)5- ligand is lost; H5(HXTA) denotes N,N′-(2-hydroxy-5-methyl-1,3-xylylene)bis(N-carboxymethylglycine). This may be attributed to the oxidative degradation of one acetato arm of the (HXTA)5- ligand due to a peroxide-Co(III) species.
KW - Cobalt complexes
KW - Oxidation of ligand system
KW - Peroxide adduct
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U2 - 10.1016/S1387-7003(99)00059-3
DO - 10.1016/S1387-7003(99)00059-3
M3 - Article
AN - SCOPUS:0033420609
SN - 1387-7003
VL - 2
SP - 244
EP - 246
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 6
ER -