Intercalation on Transition Metal Trichalcogenides via a Quasi-Amorphous Phase with 1D Order

Masaya Fujioka, Melbert Jeem, Kento Sato, Masashi Tanaka, Kazuki Morita, Taizo Shibuya, Kiyonori Takahashi, Suguru Iwasaki, Akira Miura, Masanori Nagao, Satoshi Demura, Hideaki Sakata, Madoka Ono, Hideo Kaiju, Junji Nishii

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Intercalation into 1D transition metal trichalcogenides (TMTs) in which fibers are bonded by a weak van der Waals force can be expected to create various intercalation compounds and develop unique physical properties according to the combination of the host materials and guest ions. However, structural changes via intercalation into 1D TMTs are not as simple as those in 2D transition metal dichalcogenides (TMDs) and are still not understood comprehensively. ZrTe3: a typical compound with a 1D trigonal prismatic structure, belongs to TMTs. Herein, through the Ag introduction to ZrTe3 via solid-state intercalation, a novel crystal phase with a 1D octahedral structure and a quasi-amorphous (QA) phase during the structural transition are discovered; the QA phase is a novel state of matter in which long-range order is lost while retaining 1D order. Based on the Ag concentration, the transport properties are flexibly modulated from superconductivity to semiconductivity. Density functional theory calculations indicate the attraction between Ag ions and the pair diffusion due to their attraction. Furthermore, judging the attraction or repulsion between guest ions predicts whether to induce a QA phase or simple lattice expansion like the intercalation into 2D TMDs.

本文言語English
論文番号2208702
ジャーナルAdvanced Functional Materials
33
10
DOI
出版ステータスPublished - 2023 3月 2

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 化学一般
  • 材料科学一般
  • 電気化学
  • 生体材料

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