Layer-by-layer self-assembled mesoporous PEDOT-PSS and carbon black hybrid films for platinum free dye-sensitized-solar-cell counter electrodes

Koji Kitamura, Seimei Shiratori

研究成果: Article査読

44 被引用数 (Scopus)

抄録

A thin film of poly(3,4-ethylenedioxythiophene)-poly(4-styrenesulfonic acid) (PEDOT-PSS), which is an alternative cathodic catalyst for Pt in dye-sensitized solar cells, was prepared using the layer-by-layer self-assembly method (LbL). The film is highly adhesive to the substrate and has a controllable thickness. Therefore, the PEDOT-PSS film prepared using LbL is expected have high performance and durability as a counter electrode. Moreover, when carbon black was added to the PEDOT-PSS solution, highly mesoporous PEDOT-PSS and carbon black hybrid films were obtained. These films showed high cathodic activity. In this study, we investigated the change in morphology in the obtained film with increasing carbon black content, and the influence of the porosity and thickness on the performance of the cells. In this study, a Pt-free counter electrode with performance similar to that of Pt-based counter electrodes was successfully fabricated. The achieved efficiency of 4.71% was only a factor of 8% lower than that of the cell using conventional thermally deposited Pt on fluorine-doped tin oxide glass counter electrodes.

本文言語English
論文番号195703
ジャーナルNanotechnology
22
19
DOI
出版ステータスPublished - 2011 5月 13

ASJC Scopus subject areas

  • バイオエンジニアリング
  • 化学一般
  • 材料科学一般
  • 材料力学
  • 機械工学
  • 電子工学および電気工学

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