Metal-free C-H amination of unactivated hydrocarbons with sulfonylimino-λ3-bromanes generated in situ from (diacetoxybromo)benzene

Kazunori Miyamoto; Taiga Ota; Md Mahbubul Hoque; Masahito Ochiai

doi:10.1039/c4ob02160f

Metal-free C-H amination of unactivated hydrocarbons with sulfonylimino-λ³-bromanes generated in situ from (diacetoxybromo)benzene

Kazunori Miyamoto
, Taiga Ota
, Md Mahbubul Hoque
, Masahito Ochiai

研究成果: Article › 査読

9 被引用数 (Scopus)

抄録

A simple method for direct metal-free C-H amination of unactivated hydrocarbons using easy-handling diacetoxy-λ³-bromane and triflylamide or sulfamate esters was developed. The high 2°/3° regioselectivities and deuterium isotope effects suggest a concerted organonitrenoid transition state, analogous to C-H amination with N-triflylimino-λ³-bromane.

本文言語	English
ページ（範囲）	2129-2133
ページ数	5
ジャーナル	Organic and Biomolecular Chemistry
巻	13
号	7
DOI	https://doi.org/10.1039/c4ob02160f
出版ステータス	Published - 2015 2月 21
外部発表	はい

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

文献へのアクセス

10.1039/c4ob02160f

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引用スタイル

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abstract = "A simple method for direct metal-free C-H amination of unactivated hydrocarbons using easy-handling diacetoxy-λ3-bromane and triflylamide or sulfamate esters was developed. The high 2°/3° regioselectivities and deuterium isotope effects suggest a concerted organonitrenoid transition state, analogous to C-H amination with N-triflylimino-λ3-bromane.",

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AU - Hoque, Md Mahbubul

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