Microwave specific effect on catalytic enantioselective Conia-ene reaction

Shigeki Tashima; Taichi Sawada; Kodai Saito; Tohru Yamada

doi:10.1246/cl.160200

Microwave specific effect on catalytic enantioselective Conia-ene reaction

Shigeki Tashima
, Taichi Sawada
, Kodai Saito
, Tohru Yamada

化学科

研究成果: Article › 査読

17 被引用数 (Scopus)

抄録

Microwave irradiation was applied to the enantioselective Conia-ene reaction catalyzed by Cu(OTf)₂ with a chiral amine. Under strictly controlled temperature conditions, microwave irradiation improved the chemical yields without any loss of the enantioselectivities. Consequently, the kinetic rate by the microwave irradiation was 1.15 times higher than that by conventional heating. These observations suggested that the microwave specific effects enhanced the efficiency of the enantioselective Conia-ene reaction.

本文言語	English
ページ（範囲）	649-651
ページ数	3
ジャーナル	Chemistry Letters
巻	45
号	6
DOI	https://doi.org/10.1246/cl.160200
出版ステータス	Published - 2016

ASJC Scopus subject areas

化学一般

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10.1246/cl.160200

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title = "Microwave specific effect on catalytic enantioselective Conia-ene reaction",

abstract = "Microwave irradiation was applied to the enantioselective Conia-ene reaction catalyzed by Cu(OTf)2 with a chiral amine. Under strictly controlled temperature conditions, microwave irradiation improved the chemical yields without any loss of the enantioselectivities. Consequently, the kinetic rate by the microwave irradiation was 1.15 times higher than that by conventional heating. These observations suggested that the microwave specific effects enhanced the efficiency of the enantioselective Conia-ene reaction.",

keywords = "Conia-ene reaction, Enantioselective reaction, Microwave-assisted reaction",

author = "Shigeki Tashima and Taichi Sawada and Kodai Saito and Tohru Yamada",

note = "Publisher Copyright: {\textcopyright} 2016 The Chemical Society of Japan.",

year = "2016",

doi = "10.1246/cl.160200",

language = "English",

volume = "45",

pages = "649--651",

journal = "Chemistry Letters",

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T1 - Microwave specific effect on catalytic enantioselective Conia-ene reaction

AU - Tashima, Shigeki

AU - Sawada, Taichi

AU - Saito, Kodai

AU - Yamada, Tohru

PY - 2016

Y1 - 2016

N2 - Microwave irradiation was applied to the enantioselective Conia-ene reaction catalyzed by Cu(OTf)2 with a chiral amine. Under strictly controlled temperature conditions, microwave irradiation improved the chemical yields without any loss of the enantioselectivities. Consequently, the kinetic rate by the microwave irradiation was 1.15 times higher than that by conventional heating. These observations suggested that the microwave specific effects enhanced the efficiency of the enantioselective Conia-ene reaction.

AB - Microwave irradiation was applied to the enantioselective Conia-ene reaction catalyzed by Cu(OTf)2 with a chiral amine. Under strictly controlled temperature conditions, microwave irradiation improved the chemical yields without any loss of the enantioselectivities. Consequently, the kinetic rate by the microwave irradiation was 1.15 times higher than that by conventional heating. These observations suggested that the microwave specific effects enhanced the efficiency of the enantioselective Conia-ene reaction.

KW - Conia-ene reaction

KW - Enantioselective reaction

KW - Microwave-assisted reaction

UR - https://www.scopus.com/pages/publications/84973623261

UR - https://www.scopus.com/pages/publications/84973623261#tab=citedBy

U2 - 10.1246/cl.160200

DO - 10.1246/cl.160200

M3 - Article

AN - SCOPUS:84973623261

SN - 0366-7022

VL - 45

SP - 649

EP - 651

JO - Chemistry Letters

JF - Chemistry Letters

IS - 6

ER -

Microwave specific effect on catalytic enantioselective Conia-ene reaction

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