New and efficient catalysts for enantioselective borohydride reduction of ketones and imines

Takushi Nagata; Kiyoaki D. Sugi; Kiyotaka Yorozu; Tohru Yamada; Teruaki Mukaiyama

doi:10.1023/A:1019005803704

New and efficient catalysts for enantioselective borohydride reduction of ketones and imines

Takushi Nagata, Kiyoaki D. Sugi, Kiyotaka Yorozu, Tohru Yamada, Teruaki Mukaiyama

化学科

研究成果: Article › 査読

19 被引用数 (Scopus)

抄録

Optically active aldiminato cobalt(II) complexes have been found to catalyze the enantioselective reduction of ketones with sodium borohydride affording the corresponding optically active secondary alcohols in high chemical yields with high enantioselectivities. The enantioselective borohydride reduction is also applicable to not only C=O bonds in aromatic ketones but also to C=N bonds in aromatic imines.

本文言語	English
ページ（範囲）	47-57
ページ数	11
ジャーナル	Catalysis Surveys from Japan
巻	2
号	1
DOI	https://doi.org/10.1023/A:1019005803704
出版ステータス	Published - 1998

ASJC Scopus subject areas

触媒
物理化学および理論化学

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10.1023/A:1019005803704

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abstract = "Optically active aldiminato cobalt(II) complexes have been found to catalyze the enantioselective reduction of ketones with sodium borohydride affording the corresponding optically active secondary alcohols in high chemical yields with high enantioselectivities. The enantioselective borohydride reduction is also applicable to not only C=O bonds in aromatic ketones but also to C=N bonds in aromatic imines.",

keywords = "Aromatic imine, Aromatic ketone, Borohydride, Cobalt, Enantioselective reduction, Primary amine, Secondary alcohol",

author = "Takushi Nagata and Sugi, {Kiyoaki D.} and Kiyotaka Yorozu and Tohru Yamada and Teruaki Mukaiyama",

year = "1998",

doi = "10.1023/A:1019005803704",

language = "English",

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T1 - New and efficient catalysts for enantioselective borohydride reduction of ketones and imines

AU - Nagata, Takushi

AU - Sugi, Kiyoaki D.

AU - Yorozu, Kiyotaka

AU - Yamada, Tohru

AU - Mukaiyama, Teruaki

PY - 1998

Y1 - 1998

N2 - Optically active aldiminato cobalt(II) complexes have been found to catalyze the enantioselective reduction of ketones with sodium borohydride affording the corresponding optically active secondary alcohols in high chemical yields with high enantioselectivities. The enantioselective borohydride reduction is also applicable to not only C=O bonds in aromatic ketones but also to C=N bonds in aromatic imines.

AB - Optically active aldiminato cobalt(II) complexes have been found to catalyze the enantioselective reduction of ketones with sodium borohydride affording the corresponding optically active secondary alcohols in high chemical yields with high enantioselectivities. The enantioselective borohydride reduction is also applicable to not only C=O bonds in aromatic ketones but also to C=N bonds in aromatic imines.

KW - Aromatic imine

KW - Aromatic ketone

KW - Borohydride

KW - Cobalt

KW - Enantioselective reduction

KW - Primary amine

KW - Secondary alcohol

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New and efficient catalysts for enantioselective borohydride reduction of ketones and imines

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