Newly designed catalysts for the enantioselective borohydride reduction: Prediction from the theoretical analysis

Taketo Ikeno; Izumi Iwakura; Atsushi Shibahara; Miho Hatanaka; Ai Kokura; Saiko Tanaka; Takushi Nagata; Tohru Yamada

doi:10.1246/cl.2007.738

Newly designed catalysts for the enantioselective borohydride reduction: Prediction from the theoretical analysis

Taketo Ikeno, Izumi Iwakura, Atsushi Shibahara, Miho Hatanaka, Ai Kokura, Saiko Tanaka, Takushi Nagata, Tohru Yamada

化学科

研究成果: Article › 査読

4 被引用数 (Scopus)

抄録

For the catalytic enantioselective borohydride reduction, the theoretical simulation of various axial groups in Co complex catalysts predicted that the Co-carbene complexes could be employed as efficient catalysts. The newly designed complexes generated from the Co complex and methyl diazoacetate made it possible to catalyze the enantioselective borohydride reduction in a halogen-free solvent.

本文言語	English
ページ（範囲）	738-739
ページ数	2
ジャーナル	Chemistry Letters
巻	36
号	6
DOI	https://doi.org/10.1246/cl.2007.738
出版ステータス	Published - 2007 6月 5

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.2007.738

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AU - Ikeno, Taketo

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AU - Shibahara, Atsushi

AU - Hatanaka, Miho

AU - Kokura, Ai

AU - Tanaka, Saiko

AU - Nagata, Takushi

AU - Yamada, Tohru

PY - 2007/6/5

Y1 - 2007/6/5

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AB - For the catalytic enantioselective borohydride reduction, the theoretical simulation of various axial groups in Co complex catalysts predicted that the Co-carbene complexes could be employed as efficient catalysts. The newly designed complexes generated from the Co complex and methyl diazoacetate made it possible to catalyze the enantioselective borohydride reduction in a halogen-free solvent.

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Newly designed catalysts for the enantioselective borohydride reduction: Prediction from the theoretical analysis

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