TY - JOUR
T1 - [N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)
AU - Hoshina, Gakuse
AU - Ohba, Shigeru
AU - Tsuchimoto, Masanobu
PY - 1999/9/15
Y1 - 1999/9/15
N2 - The title complex, [VO(C30H24N2O4)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the VIV atom is distorted square pyramidal. The V=O distance is 1.588 (3) Å, and the V atom is displaced by 0.57 (1) Å from the N2O2 coordination plane towards the apical oxo ligand. † Alternative name: {4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′}oxovanadium(IV).
AB - The title complex, [VO(C30H24N2O4)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the VIV atom is distorted square pyramidal. The V=O distance is 1.588 (3) Å, and the V atom is displaced by 0.57 (1) Å from the N2O2 coordination plane towards the apical oxo ligand. † Alternative name: {4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′}oxovanadium(IV).
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U2 - 10.1107/S0108270199006551
DO - 10.1107/S0108270199006551
M3 - Article
AN - SCOPUS:0347649564
SN - 0108-2701
VL - 55
SP - 1451
EP - 1453
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 9
ER -