[N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)

Gakuse Hoshina; Shigeru Ohba; Masanobu Tsuchimoto

doi:10.1107/S0108270199006551

[N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)

Gakuse Hoshina
, Shigeru Ohba
, Masanobu Tsuchimoto

人文社会学科

研究成果: Article › 査読

3 被引用数 (Scopus)

抄録

The title complex, [VO(C₃₀H₂₄N₂O₄)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the V^IV atom is distorted square pyramidal. The V=O distance is 1.588 (3) Å, and the V atom is displaced by 0.57 (1) Å from the N₂O₂ coordination plane towards the apical oxo ligand. † Alternative name: {4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′}oxovanadium(IV).

本文言語	English
ページ（範囲）	1451-1453
ページ数	3
ジャーナル	Acta Crystallographica Section C: Crystal Structure Communications
巻	55
号	9
DOI	https://doi.org/10.1107/S0108270199006551
出版ステータス	Published - 1999 9月 15

ASJC Scopus subject areas

生化学、遺伝学、分子生物学一般

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10.1107/S0108270199006551

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@article{45b3982dae9048e49be39de9d288525f,

title = "[N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)",

abstract = "The title complex, [VO(C30H24N2O4)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the VIV atom is distorted square pyramidal. The V=O distance is 1.588 (3) {\AA}, and the V atom is displaced by 0.57 (1) {\AA} from the N2O2 coordination plane towards the apical oxo ligand. † Alternative name: \{4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′\}oxovanadium(IV).",

author = "Gakuse Hoshina and Shigeru Ohba and Masanobu Tsuchimoto",

year = "1999",

month = sep,

day = "15",

doi = "10.1107/S0108270199006551",

language = "English",

volume = "55",

pages = "1451--1453",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "9",

}

TY - JOUR

T1 - [N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)

AU - Hoshina, Gakuse

AU - Ohba, Shigeru

AU - Tsuchimoto, Masanobu

PY - 1999/9/15

Y1 - 1999/9/15

N2 - The title complex, [VO(C30H24N2O4)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the VIV atom is distorted square pyramidal. The V=O distance is 1.588 (3) Å, and the V atom is displaced by 0.57 (1) Å from the N2O2 coordination plane towards the apical oxo ligand. † Alternative name: {4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′}oxovanadium(IV).

AB - The title complex, [VO(C30H24N2O4)], adopts a monomeric structure in the crystals, which are red due to the charge-transfer band from the conjugated π-system of the tetradentate Schiff base ligand. The geometry around the VIV atom is distorted square pyramidal. The V=O distance is 1.588 (3) Å, and the V atom is displaced by 0.57 (1) Å from the N2O2 coordination plane towards the apical oxo ligand. † Alternative name: {4,4′-dimethoxy-2,2′-[1,2-diphenylethene-1,2- diylbis(nitrilomethylidyne)]diphenolato-O,N,N′,O′}oxovanadium(IV).

UR - https://www.scopus.com/pages/publications/0347649564

UR - https://www.scopus.com/pages/publications/0347649564#tab=citedBy

U2 - 10.1107/S0108270199006551

DO - 10.1107/S0108270199006551

M3 - Article

AN - SCOPUS:0347649564

SN - 0108-2701

VL - 55

SP - 1451

EP - 1453

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 9

ER -

[N,N′-Bis(5-methoxysalicylidene)-1,2-diphenyl-1,2-ethenediamine]- oxovanadium(IV)

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