N2O oxidation of phosphines catalyzed by low-valent nickel complexes

Tohru Yamada, Kyosuke Suzuki, Kentaro Hashimoto, Taketo Ikeno

研究成果: Article査読

27 被引用数 (Scopus)

抄録

In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)2 or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N2O; oxidation and were recovered after the reaction.

本文言語English
ページ(範囲)1043-1044
ページ数2
ジャーナルChemistry Letters
10
DOI
出版ステータスPublished - 1999

ASJC Scopus subject areas

  • 化学一般

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