Optical resolution of chiral buckybowls by chiral HPLC

Ryoji Tsuruoka, Shuhei Higashibayashi, Takeharu Ishikawa, Shinji Toyota, Hidehiro Sakurai

研究成果: Article査読

40 被引用数 (Scopus)

抄録

Optical resolution of chiral buckybowls, C3 symmetric trimethylsumanene derivatives, was achieved by chiral HPLC. Enantiomeric excess (ee) of enatioselectively prepared trimethyltris(trimethylsilyl)sumanene was determined by the chiral HPLC analysis. The enantiomers of racemic trimethylsumanenetrione were separated, and the bowl inversion energy barrier was determined by the CD spectra.

本文言語English
ページ(範囲)646-647
ページ数2
ジャーナルChemistry Letters
39
6
DOI
出版ステータスPublished - 2010
外部発表はい

ASJC Scopus subject areas

  • 化学一般

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