抄録
Among various aldiminato metal complexes, the optically active cobalt(II) complex efficiently catalyzed the enantioselective hetero Diels- Alder reaction of aromatic aldehydes with 1-methoxy-[3-(tert- butyldimethylsilyl)oxy]1,3-butadiene. In the presence of 0.5 mol% of the catalyst, the reaction smoothly proceeded and ortho substituents of the dienophiles that could chelate to the catalyst significantly accelerated the reaction to improve the chemical and optical yields.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 1041-1045 |
| ページ数 | 5 |
| ジャーナル | Heterocycles |
| 巻 | 52 |
| 号 | 3 |
| DOI | |
| 出版ステータス | Published - 2000 3月 1 |
ASJC Scopus subject areas
- 分析化学
- 薬理学
- 有機化学