Oxidative protonolysis of the expanded central CC bond in a di(spiroacridan)-type hexaphenylethane derivative accompanied by UVvis, FL, and CD spectral changes

Takanori Suzuki, Yusuke Kuroda, Kazuhisa Wada, Yuto Sakano, Ryo Katoono, Kenshu Fujiwara, Fumitoshi Kakiuchi, Takanori Fukushima

研究成果: Article査読

15 被引用数 (Scopus)

抄録

Upon electrochemical oxidation of configurationally stable (M)-4, 5-dimethyl-9, 10-dihydrophenanthrene attached with two spiroacridan units at the C9 and C10 positions [(M)-1c], a threeway-output response by UVvis, FL, and CD spectra was realized via clean conversion to the corresponding bond-dissociated dication (Rax)-2c2+. Similar gradual changes were induced upon standing of an aerated MeCN solution of (M)-1c after the addition of CF3CO2H because the elongated C9C10 bond was also cleaved by oxidative protonolysis to give (Rax)-2c2+.

本文言語English
ページ(範囲)887-889
ページ数3
ジャーナルChemistry Letters
43
6
DOI
出版ステータスPublished - 2014

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「Oxidative protonolysis of the expanded central CC bond in a di(spiroacridan)-type hexaphenylethane derivative accompanied by UVvis, FL, and CD spectral changes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル