Palladium-catalyzed electrochemical C(sp3)-H acetoxylation of alcohol derivatives with an exo-directing group

Daisuke Ogawa; Ayumu Sasaki; Takuya Kochi; Fumitoshi Kakiuchi

doi:10.1039/d4ob01241k

Palladium-catalyzed electrochemical C(sp³)-H acetoxylation of alcohol derivatives with an exo-directing group

Daisuke Ogawa, Ayumu Sasaki, Takuya Kochi, Fumitoshi Kakiuchi

化学科

研究成果: Article › 査読

1 被引用数 (Scopus)

抄録

Palladium-catalyzed electrochemical C(sp³)-H acetoxylation to prepare 1,2-diol derivatives was achieved using oxime ethers as exo-directing groups. Various substrates containing alkoxy groups with a methyl branch at the α-position as well as norbornan-2-ol derivative were acetoxylated only using a catalytic amount of Pd(OAc)₂ along with NaOAc/Ac₂O/AcOH under anodic oxidation conditions.

本文言語	English
ページ（範囲）	7696-7701
ページ数	6
ジャーナル	Organic and Biomolecular Chemistry
巻	22
号	37
DOI	https://doi.org/10.1039/d4ob01241k
出版ステータス	Published - 2024 9月 2

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

文献へのアクセス

10.1039/d4ob01241k

他のファイルとリンク

引用スタイル

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