Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl]acetylene] and the Magnetic Property of Its Radical Derivative

Hiroyuki Nishide; Takashi Kaneko; Naoki Yoshioka; Haruhisa Akiyama; Masukazu Igarashi; Eishun Tsuchida

doi:10.1021/ma00069a023

Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl]acetylene] and the Magnetic Property of Its Radical Derivative

Hiroyuki Nishide
, Takashi Kaneko
, Naoki Yoshioka
, Haruhisa Akiyama
, Masukazu Igarashi
, Eishun Tsuchida

研究成果: Article › 査読

45 被引用数 (Scopus)

抄録

[4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly [[4-(N-tert-butyl-N-hydroxyamino)phenyl] acetylene] (8). Oxidation of the polymer gave its radical derivative: the ESR spectrum showed a broad signal only in the Δm₈ = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

本文言語	English
ページ（範囲）	4567-4571
ページ数	5
ジャーナル	Macromolecules
巻	26
号	17
DOI	https://doi.org/10.1021/ma00069a023
出版ステータス	Published - 1993
外部発表	はい

ASJC Scopus subject areas

有機化学
ポリマーおよびプラスチック
無機化学
材料化学

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10.1021/ma00069a023

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author = "Hiroyuki Nishide and Takashi Kaneko and Naoki Yoshioka and Haruhisa Akiyama and Masukazu Igarashi and Eishun Tsuchida",

year = "1993",

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T1 - Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl]acetylene] and the Magnetic Property of Its Radical Derivative

AU - Nishide, Hiroyuki

AU - Kaneko, Takashi

AU - Yoshioka, Naoki

AU - Akiyama, Haruhisa

AU - Igarashi, Masukazu

AU - Tsuchida, Eishun

PY - 1993

Y1 - 1993

N2 - [4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly [[4-(N-tert-butyl-N-hydroxyamino)phenyl] acetylene] (8). Oxidation of the polymer gave its radical derivative: the ESR spectrum showed a broad signal only in the Δm8 = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

AB - [4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly [[4-(N-tert-butyl-N-hydroxyamino)phenyl] acetylene] (8). Oxidation of the polymer gave its radical derivative: the ESR spectrum showed a broad signal only in the Δm8 = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

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UR - https://www.scopus.com/pages/publications/0027649846#tab=citedBy

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AN - SCOPUS:0027649846

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JO - Macromolecules

JF - Macromolecules

IS - 17

ER -

Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl]acetylene] and the Magnetic Property of Its Radical Derivative

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