Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure

Masanobu Tsuchimoto; Hirofumi Iwamoto; Masaaki Kojima; Shigeru Ohba

doi:10.1246/cl.2000.1156

Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure

Masanobu Tsuchimoto
, Hirofumi Iwamoto
, Masaaki Kojima
, Shigeru Ohba

人文社会学科

研究成果: Article › 査読

10 被引用数 (Scopus)

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A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H₂(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN₃salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.

本文言語	English
ページ（範囲）	1156-1157
ページ数	2
ジャーナル	Chemistry Letters
号	10
DOI	https://doi.org/10.1246/cl.2000.1156
出版ステータス	Published - 2000

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化学一般

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10.1246/cl.2000.1156

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author = "Masanobu Tsuchimoto and Hirofumi Iwamoto and Masaaki Kojima and Shigeru Ohba",

year = "2000",

doi = "10.1246/cl.2000.1156",

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AU - Tsuchimoto, Masanobu

AU - Iwamoto, Hirofumi

AU - Kojima, Masaaki

AU - Ohba, Shigeru

PY - 2000

Y1 - 2000

N2 - A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H2(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN3salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.

AB - A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H2(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN3salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.

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SP - 1156

EP - 1157

JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure

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