@article{e8ac00e81571429d81f0677628a393d4,
title = "Recent advances in boron-mediated aglycon delivery (BMAD) for the efficient synthesis of 1,2-cis glycosides",
abstract = "Highly stereoselective synthesis of 1,2-cis glycosides remains a challenging task due to the lack of reliable neighboring group participation (NGP) from the 2-O-acyl functionality in the glycosyl donor. In this context, our group recently developed highly 1,2-cis-stereoselective glycosylation methods, named boron-mediated aglycon delivery (BMAD), using organoboron reagents and 1,2-anhydroglycosyl donors. In this mini-review article, we introduce the BMAD methods and their applications to the synthesis of biologically active natural products and complex glycosides reported since our mini-review article published in this journal in 2017.",
keywords = "1,2-cis glycoside, Boron-mediated aglycon delivery, Glycosylation, Natural products, Regioselective, Stereoselective",
author = "Daisuke Takahashi and Kazuki Inaba and Kazunobu Toshima",
note = "Funding Information: This research was supported in part by the MEXT -supported Program for the Strategic Research Foundation at Private Universities, 2012–2016 ( S1201020 ), and JSPS KAKENHI Grant Numbers JP16H01161 in Middle Molecular Strategy, JP16K05781 in Scientific Research (C), JP18J12129 in JSPS Fellows, JP19J13223 in JSPS Fellows, JP19H02724 in Scientific Research (B) and JP20K21289 in Challenging Research (Exploratory), a SUNBOR Grant from the Suntory Foundation for Life Sciences, and the Sasagawa Scientific Research Grant from the Japan Science Society . Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",
year = "2022",
month = aug,
doi = "10.1016/j.carres.2022.108579",
language = "English",
volume = "518",
journal = "Carbohydrate Research",
issn = "0008-6215",
publisher = "Elsevier BV",
}