抄録
The regioselectivities observed in Baeyer-Villiger reaction of polyhydroxycyclohexanone derivatives possessing various substituents at adjacent carbons to the ketone carbonyl are reported. This study suggested that the trend of the migratory aptitude of substituted carbons would be a carbon with benzyloxy > methoxy > ketal oxygen ≫ acyloxy ∼ methyl.
本文言語 | English |
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ページ(範囲) | 7249-7252 |
ページ数 | 4 |
ジャーナル | Tetrahedron Letters |
巻 | 35 |
号 | 39 |
DOI | |
出版ステータス | Published - 1994 9月 26 |
ASJC Scopus subject areas
- 生化学
- 創薬
- 有機化学