@article{3f9bbc370b1143f8bfeb69a46157eed0,
title = "Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β-Acetoxy Elimination",
abstract = "Palladium-catalyzed remote arylative substitution was achieved for the reaction of arylboronic acids with alkenes possessing a distant acetoxy group to provide arylation products having an alkene moiety at the remote position. The use of β-acetoxy elimination as a key step in the catalytic cycle allowed for regioselective formation of unstabilized alkenes after chain walking. This reaction was applicable to various arylboronic acids as well as alkene substrates.",
keywords = "alkenes, arylation, chain walking, palladium, β-acetoxy elimination",
author = "Kazuma Muto and Takaaki Kumagai and Fumitoshi Kakiuchi and Takuya Kochi",
note = "Funding Information: This work was supported, in part, by JSPS KAKENHI Grant Numbers, JP18H01985 (Grant‐in‐Aid for Scientific Research (B)), and JP15KT0069 (Grant‐in‐Aid for Scientific Research (B)) as well as the Asahi Glass Foundation. K.M. is also grateful for support by the Keio University Doctorate Student Grant‐in‐Aid Program from Ushioda Memorial Fund. Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",
year = "2021",
month = nov,
day = "8",
doi = "10.1002/anie.202111396",
language = "English",
volume = "60",
pages = "24500--24504",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "46",
}