Rhodium-Catalyzed β-Acylalkylation of Allylbenzene Derivatives with Allyl Alcohols via C-C Bond Cleavage

Soya Ishikawa, Ryo Togashi, Ryosuke Ueda, Shunsuke Onodera, Takuya Kochi, Fumitoshi Kakiuchi

研究成果: Article査読

3 被引用数 (Scopus)

抄録

We report here a deallylative β-acylalkylation reaction of allylbenzene derivatives with allyl alcohols in the presence of Cp*Rh catalysts. Allylbenzenes possessing pyridyl and pyrazolyl directing groups were converted to β-aryl ketones via the cleavage of C(aryl)-C(allyl) bonds. Synthesis of a quinoline derivative from a β-aryl ketone product bearing a pyrazolyl group was also achieved.

本文言語English
ページ(範囲)3313-3320
ページ数8
ジャーナルJournal of Organic Chemistry
88
5
DOI
出版ステータスPublished - 2023 3月 3

ASJC Scopus subject areas

  • 有機化学

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