Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges

Satoshi Nishino; Hiroyuki Hosomi; Shigeru Ohba; Hideaki Matsushima; Tadashi Tokii; Yuzo Nishida

doi:10.1039/a809725i

Selective dioxygenation of cyclohexane catalysed by hydrogen peroxide and dinuclear iron(III) complexes with μ-alkoxo bridges

Satoshi Nishino, Hiroyuki Hosomi, Shigeru Ohba, Hideaki Matsushima, Tadashi Tokii, Yuzo Nishida

人文社会学科

研究成果: Article › 査読

30 被引用数 (Scopus)

抄録

Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

本文言語	English
ページ（範囲）	1509-1513
ページ数	5
ジャーナル	Journal of the Chemical Society - Dalton Transactions
号	9
DOI	https://doi.org/10.1039/a809725i
出版ステータス	Published - 1999 5月 7

ASJC Scopus subject areas

化学 (全般)

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10.1039/a809725i

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引用スタイル

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AU - Hosomi, Hiroyuki

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AU - Matsushima, Hideaki

AU - Tokii, Tadashi

AU - Nishida, Yuzo

PY - 1999/5/7

Y1 - 1999/5/7

N2 - Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

AB - Several dinuclear iron(III) complexes with μ-alkoxo bridges gave predominantly cyclohexyl hydroperoxide in the reaction with cyclohexane and hydrogen peroxide, and similar results were observed when linear n-alkanes, such as n-nonane and n-octane, were used instead of cyclohexane. A mechanism for selective formation of the hydroperoxide is discussed.

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