抄録
(Chemical Equation Presented) Iodoalkoxylation (see scheme) of a glycal with an acyclic saccharide precursor leads to an efficient stereoselective synthesis of di- and tri-α(2,8)-3-deoxy-D-manno-2-octulosonic acid (KDO; see picture). The glycal forms α-linked 3-iodo-KDO derivatives. The opening of the pyran ring improves the reactivity of the C8 hydroxy group. NIS = N-iodosuccimide, Tf = triflate, M.S. = molecular sieves.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 770-773 |
| ページ数 | 4 |
| ジャーナル | Angewandte Chemie - International Edition |
| 巻 | 45 |
| 号 | 5 |
| DOI | |
| 出版ステータス | Published - 2006 1月 23 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 触媒
- 化学 (全般)