Structural characteristics and optical properties of a series of solvatochromic fluorescent dyes displaying long-wavelength emission

Yosuke Ando, Yuya Homma, Yuki Hiruta, Daniel Citterio, Koji Suzuki

研究成果: Article査読

32 被引用数 (Scopus)

抄録

A series of novel, fluorescent, solvatochromic dyes (KSD-series) carrying a 4-dimethylaminophenyl moiety as π-electron donor and an acetyl moiety as π-electron acceptor, conjugated with a five-membered aromatic monoheterocyclic π-linker, were synthesized. In the cases of dyes having a pyrrole, (KSD-1) furan (KSD-2) and thiophene (KSD-3) heterocycle as π-linker, respectively, the plot of Stokes shifts in different solvents as a function of ET(30) solvent polarity value showed good linear correlation. The fluorescence of KSD-4, a π-conjugation extended derivative of KSD-3, varied from blue (491 nm) in toluene to orange (616 nm) in DMSO; KSD-4C, a carboxyl group modified derivative, displayed longer wavelength emission (619 nm) and larger Stokes shift (229 nm, 9486 cm-1) than conventional dyes in methanol solution.

本文言語English
ページ(範囲)198-206
ページ数9
ジャーナルDyes and Pigments
83
2
DOI
出版ステータスPublished - 2009 11月

ASJC Scopus subject areas

  • 化学工学一般
  • プロセス化学およびプロセス工学

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