Structure and reactivity of bimetallic ConVm+ cluster ions

Atsushi Nakajima; Takashi Kishi; Tsuneyoshi Sugioka; Yasutomo Sone; Koji Kaya

doi:10.1021/j100171a019

Structure and reactivity of bimetallic Co_nV_m⁺ cluster ions

Atsushi Nakajima, Takashi Kishi, Tsuneyoshi Sugioka, Yasutomo Sone, Koji Kaya

化学科

研究成果: Article › 査読

29 被引用数 (Scopus)

抄録

The reaction of bimetallic Co_nV_m⁺ cluster ions, generated by laser vaporization, toward hydrogen was investigated by using a fast-flow reactor. Compared with pure Co_n⁺ cluster ions, the reactivity of Co_n-1V⁺ cluster ions exhibits a drastic decrease at n ≥ 13 similar to that of neutral Co_nV_m clusters. The result can be explained in terms of their geometrical structure; at n ≥ 13, the V atom is located at the center of the cluster and is surrounded by Co atoms.

本文言語	English
ページ（範囲）	6833-6835
ページ数	3
ジャーナル	Journal of Physical Chemistry
巻	95
号	18
DOI	https://doi.org/10.1021/j100171a019
出版ステータス	Published - 1991 1月 1

ASJC Scopus subject areas

工学（全般）
物理化学および理論化学

文献へのアクセス

10.1021/j100171a019

他のファイルとリンク

引用スタイル

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