Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Masanobu Tsuchimoto; Hirofumi Iwamoto; Masaaki Kojima; Shigeru Ohba

doi:10.1080/10587250210760

Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand

Masanobu Tsuchimoto, Hirofumi Iwamoto, Masaaki Kojima, Shigeru Ohba

人文社会学科

研究成果: Conference article › 査読

1 被引用数 (Scopus)

抄録

Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H₂(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

本文言語	English
ページ（範囲）	33-38
ページ数	6
ジャーナル	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
巻	376
DOI	https://doi.org/10.1080/10587250210760
出版ステータス	Published - 2002
イベント	Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States 継続期間: 2000 12月 15 → 2000 12月 18

ASJC Scopus subject areas

凝縮系物理学

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10.1080/10587250210760

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Synthesis and crystal structures of polymeric nitridomanganese(V) and nitridochromium(V) complexes with a tetradentate schiff base ligand. / Tsuchimoto, Masanobu; Iwamoto, Hirofumi; Kojima, Masaaki その他.
In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 376, 2002, p. 33-38.

研究成果: Conference article › 査読

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abstract = "Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) {\AA} for M=Mn, and 2.508(2) {\AA} for M=Cr.",

keywords = "Nitridochromium(V) complex, Nitridomanganese(V) complex, Polymeric structure",

author = "Masanobu Tsuchimoto and Hirofumi Iwamoto and Masaaki Kojima and Shigeru Ohba",

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note = "Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids ; Conference date: 15-12-2000 Through 18-12-2000",

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AU - Tsuchimoto, Masanobu

AU - Iwamoto, Hirofumi

AU - Kojima, Masaaki

AU - Ohba, Shigeru

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N2 - Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

AB - Novel polymeric nitridomanganese(V) and nitridochromium(V) complexes with a Schiff base ligand, [MnN(salpn)] and [CrN(salpn)] (H2(salpn): N,N'-disalicylidene-1,3-propanediamine) were prepared by photolysis of azido complexes. X-ray crystal structure analyses show that the complexes have an isostructual polymeric structure (⋯M≡N⋯M≡N⋯) with the N⋯M distances being 2.528(3) Å for M=Mn, and 2.508(2) Å for M=Cr.

KW - Nitridochromium(V) complex

KW - Nitridomanganese(V) complex

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