Synthetic Route to 2-Deoxyaldoses by Fluoride-Catalyzed Solvolysis of Enol-Phosphate Esters

Naoki Mitsuo, Yoshihiro Abe, Takeo Takizawa, Takehisa Kunieda

研究成果: Article査読

2 被引用数 (Scopus)

抄録

1-Alkenyl and phenyl phosphate esters undergo smooth cleavage of the phosphorus-oxygen linkage by fluoride-catalyzed alcoholysis to give aldehydes (ketones) and phenols, respectively. Application of this method provides a new route to 2-deoxyaldosugars from the enol-phosphates derived from vinylene carbonate telomers.

本文言語English
ページ(範囲)1327-1330
ページ数4
ジャーナルChemical and Pharmaceutical Bulletin
28
4
DOI
出版ステータスPublished - 1980

ASJC Scopus subject areas

  • 化学 (全般)
  • 創薬

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